名校
1 . 酯类化合物与格氏试剂(RMgX,X=Cl、Br、I)的反应是合成叔醇类化合物的重要方法,可用于制备含氧多官能团化合物。化合物F合成路线如下,回答下列问题:
![](https://img.xkw.com/dksih/QBM/2020/12/11/2611765904932864/2612598056845312/STEM/b4482205602947a4a8ef4ff745956eac.png?resizew=554)
已知信息如下:①RCH=CH2
RCH2CH2OH
②![](https://img.xkw.com/dksih/QBM/2020/12/11/2611765904932864/2612598056845312/STEM/d689769137ca44679c08fdf6619e4a86.png?resizew=207)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/8186391aa51055c275084b7461a7a2c6.png)
![](https://img.xkw.com/dksih/QBM/2020/12/11/2611765904932864/2612598056845312/STEM/7fa4e53b-2d95-4647-9dcb-3ed35c0aec63.png?resizew=44)
③RCOOCH3![](https://staticzujuan.xkw.com/quesimg/Upload/formula/40e554771916ab6d53fad0ea2837bd09.png)
![](https://img.xkw.com/dksih/QBM/2020/12/11/2611765904932864/2612598056845312/STEM/0d51c5abcf8146cea28c939d0950dc89.png?resizew=76)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/40e554771916ab6d53fad0ea2837bd09.png)
![](https://img.xkw.com/dksih/QBM/2020/12/11/2611765904932864/2612598056845312/STEM/5c3e1fba60cc4576951e09785aa1f966.png?resizew=86)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/8186391aa51055c275084b7461a7a2c6.png)
![](https://img.xkw.com/dksih/QBM/2020/12/11/2611765904932864/2612598056845312/STEM/360276507d43494d9942dd8709fb03da.png?resizew=86)
(1)A的结构简式为_________ ,B→C的反应类型为________ ,C中官能团的名称为________ ,C→D的反应方程式为________ 。
(2)写出符合下列条件的D的同分异构体:________ (填结构简式,不考虑立体异构)。
①含有五元碳环结构; ②能与NaHCO3溶液反应放出CO2; ③能发生银镜反应。
(3)判断化合物F中有无手性碳原子,若有则用“*”标出___________ 。
(4)已知羟基能与格氏试剂发生反应。写出以
、CH3OH和格氏试剂为原料制备
的合成路线(其他试剂任选)_________ 。
![](https://img.xkw.com/dksih/QBM/2020/12/11/2611765904932864/2612598056845312/STEM/b4482205602947a4a8ef4ff745956eac.png?resizew=554)
已知信息如下:①RCH=CH2
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/bba6062e71a833efd87841a47ac480a0.png)
②
![](https://img.xkw.com/dksih/QBM/2020/12/11/2611765904932864/2612598056845312/STEM/d689769137ca44679c08fdf6619e4a86.png?resizew=207)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/8186391aa51055c275084b7461a7a2c6.png)
![](https://img.xkw.com/dksih/QBM/2020/12/11/2611765904932864/2612598056845312/STEM/7fa4e53b-2d95-4647-9dcb-3ed35c0aec63.png?resizew=44)
③RCOOCH3
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/40e554771916ab6d53fad0ea2837bd09.png)
![](https://img.xkw.com/dksih/QBM/2020/12/11/2611765904932864/2612598056845312/STEM/0d51c5abcf8146cea28c939d0950dc89.png?resizew=76)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/40e554771916ab6d53fad0ea2837bd09.png)
![](https://img.xkw.com/dksih/QBM/2020/12/11/2611765904932864/2612598056845312/STEM/5c3e1fba60cc4576951e09785aa1f966.png?resizew=86)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/8186391aa51055c275084b7461a7a2c6.png)
![](https://img.xkw.com/dksih/QBM/2020/12/11/2611765904932864/2612598056845312/STEM/360276507d43494d9942dd8709fb03da.png?resizew=86)
(1)A的结构简式为
(2)写出符合下列条件的D的同分异构体:
①含有五元碳环结构; ②能与NaHCO3溶液反应放出CO2; ③能发生银镜反应。
(3)判断化合物F中有无手性碳原子,若有则用“*”标出
(4)已知羟基能与格氏试剂发生反应。写出以
![](https://img.xkw.com/dksih/QBM/2020/12/11/2611765904932864/2612598056845312/STEM/745308de-779c-4126-92b5-888db0ef50a5.png?resizew=118)
![](https://img.xkw.com/dksih/QBM/2020/12/11/2611765904932864/2612598056845312/STEM/25cb92bbf4bb4930aa5fb2e3174a28bf.png?resizew=108)
您最近一年使用:0次
2020-12-12更新
|
586次组卷
|
9卷引用:山东省2020年普通高中学业水平等级考试模拟试题
山东省2020年普通高中学业水平等级考试模拟试题【省级联考】山东省2020届新高考模拟统考化学试题湖南省长沙市长郡中学2020届高三月考(六)理综化学试题河南省洛阳市2020届高三上学期期末模拟考试化学试题(已下线)考点19 有机合成与推断-2020年高考化学命题预测与模拟试题分类精编(已下线)第34讲 生命中的基础有机化学物质 合成有机高分子(精练)-2021年高考化学一轮复习讲练测广东省河源中学2021届高三上学期第二次质量检测化学试题黑龙江省哈尔滨市第六中学2020-2021学年高二下学期期末考试化学试题(已下线)专题14 有机化学基础—2022年高考化学二轮复习讲练测(全国版)-测试