![](https://staticzujuan.xkw.com/quesimg/Upload/formula/2b32054d67c2719ade864530c97c17e3.png)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/c523e50f790218235eae777f95a8a724.png)
A.该反应在高温条件下可以自发进行 |
B.向反应容器中加入催化剂,反应自发进行的临界温度会降低 |
C.恒容条件下,通入He和Ar组成的混合气体,压强会增大,反应的速率会加快 |
D.恒容条件下,可通入过量的CO2气体来提高![]() ![]() |
2 . 阿根廷科学家MasVeronica等人利用Ni(Ⅱ)Al(Ⅲ)层状复合催化剂进行了乙醇水蒸气重整制氢的研究。其主要反应为
反应I.C2H5OH(g)+3H2O(g)=2CO2(g)+6H2(g) △H1=+173.3kJ/mol △S=+362.7J/(K•mol)
反应Ⅱ.C2H5OH(g)+H2O(g)=2CO(g)+4H2(g) △H2=+255.7kJ/mol
若在恒容密闭容器中发生上述反应。
(1)反应I在常温下
(2)对上述恒容密闭容器中的体系,下列说法正确的是
A.增大H2O(g)的浓度,有利于提高C2H5OH平衡转化率 |
B.一定温度下,增大C2H5OH的浓度可以提高C2H5OH的平衡转化率 |
C.若气体的平均相对分子质量保持不变,说明反应体系已达平衡 |
D.升高温度可以使反应I、Ⅱ的正反应速率加快,逆反应速率减小,平衡向正反应方向移动 |
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/03035558c7c25f1d860ba1e8f358835c.png)
①图中曲线表示平衡时H2产率随温度变化的曲线是
②在密闭容器中,以投料比n(C2H5OH):n(H2O)=3:8通入混合气体,此时C2H5OH的转化率为66.67%,求交点M坐标为(500℃,50%)时反应Ⅱ的平衡常数Kp=
③一定能提高CO选择性的关键因素是
④请分析说明曲线②随温度变化的原因
(4)对乙醇水蒸气重整制氢反应I进行反应机理分析如下,“*”表示催化剂表面的活性中心,请补充完成基元反应iii。
i.C2H6O(g)+(*)→C2H6O*
ii.C2H6O*+(*)→CH4O*+CH2*
ⅲ.
iv.CH2*+2H2O(g)→CO2(g)+3H2(g)+(*)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/0fd072fc58b4a4ae103ad82d135626b9.png)
A.低温下能自发进行 | B.高温下能自发进行 |
C.任何温度下都不能自发进行 | D.任何温度下都能自发进行 |
反应I:
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/7f0fb442bc45cdf5f9e959d6ca595ac5.png)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/6fbb5d519f981a09188dc18a765e8c43.png)
应Ⅱ:
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/5a1aa90a487c4614d8c5d963b2c0d5fc.png)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/7e3396e9e066adc1d6e03779938058a9.png)
反应Ⅲ:
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/261c492d5506479e5b4249032a04ece6.png)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/a95d800b889e9e22aa00ec16b7f0a794.png)
回答下列问题:
(1)①反应I、Ⅱ、Ⅲ的平衡常数
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/9c844a8c678719406417282f0b548417.png)
![](https://img.xkw.com/dksih/QBM/editorImg/2023/4/28/0d3b0ae3-2c37-40ab-b7bc-46f85063a1b8.png?resizew=233)
A.在任何温度下都不能 B.在任何温度下都能 C.在低温下能 D.在高温下能
②
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/e5065b62f6c0e373af05e3824cab4449.png)
A.<-1 B.-1~0 C.0~1 D.>1
(2)为研究上述反应体系的平衡关系,向VL某反应容器中加入a mol D(g),控制温度为353K,保持容积不变,测得D(g)的平衡转化率为b。该温度下已知反应Ⅲ的平衡常数
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/8d1be5f68c4f6da9e55d5158c5701ecf.png)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/925d2cb8d6b5b6065eda7d2fe8c24724.png)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/9aa774c57abc2c4833251330768ecee6.png)
(3)为研究反应体系的动力学行为,向另一容器中加入一定量A(g)、B(g)、C(g)。控制温度为353K,A(g)、B(g)物质的量浓度c随反应时间t的变化如图2所示。代表B(g)变化曲线为
![](https://img.xkw.com/dksih/QBM/editorImg/2023/4/28/c549e5c2-8c0a-4431-91bf-893aafc2a033.png?resizew=236)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/a4144cd792e828b9a97692ecdfda55f3.png)
![](https://img.xkw.com/dksih/QBM/editorImg/2024/1/30/ed41b79e-c65a-4830-a8fc-84b26907977f.png?resizew=437)
已知:碳热还原
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/a4144cd792e828b9a97692ecdfda55f3.png)
ⅰ.
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/da08f36f57b6bdc6fe5b55c7e18773cb.png)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/6fbb5d519f981a09188dc18a765e8c43.png)
ⅱ.
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/437edd5b32ad8cf34163b159188860ac.png)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/b15448c170be583ee7a5b8b3ab047033.png)
ⅲ.
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/b3c6bc08e65d531f964d8539ca318e8c.png)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/04387cb2cb8a089b8d06d3f28397d24e.png)
下列关于碳热还原
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/a4144cd792e828b9a97692ecdfda55f3.png)
A.![]() |
B.反应ⅱ在高温条件下自发进行 |
C.温度升高,![]() |
D.反应过程中,生成的![]() |
I.
(1)闪电时空气中的
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/f5547e0098754a8e3f31bae5d5bcb4dd.png)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/1e762a80c1216318892c2155bef79681.png)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/90e6ae6dc9709bf3d9cc3c1fd1b88ea9.png)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/c9098ec129dfa0926ff580c82c651577.png)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/156716c327807f8a111c91081e2e3567.png)
A.在1000℃时,此反应能自发进行 |
B.在1000℃时,此反应不能自发进行 |
C.该反应能自发进行的最低温度约为730℃ |
D.该反应能自发进行的最高温度约为![]() |
II.已知
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/0cfa94a74f46029622dcc61ead545530.png)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/f310ce4fbe25d4fb7817ac5f2f72f6ee.png)
(2)该温度下,向
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/c424e9f778fdc2a13a59898ab0ccbbe3.png)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/f5547e0098754a8e3f31bae5d5bcb4dd.png)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/1e762a80c1216318892c2155bef79681.png)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/26edabbe2c43af4e74203ad34c4eff2d.png)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/f5547e0098754a8e3f31bae5d5bcb4dd.png)
(3)该温度下,某时刻测得容器内
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/f5547e0098754a8e3f31bae5d5bcb4dd.png)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/1e762a80c1216318892c2155bef79681.png)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/9110e80d125190c4b5bed606e1fc2220.png)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/13aac2b52ec9e51aab43fff1be042fe0.png)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/a15f1f442d19ce8a5ae75f59db5e4eb4.png)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/36a142ed835340acad75caa3b18aa472.png)
(4)将
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/f5547e0098754a8e3f31bae5d5bcb4dd.png)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/1e762a80c1216318892c2155bef79681.png)
A.
![](https://img.xkw.com/dksih/QBM/2023/4/15/3216884028104704/3217150769397760/STEM/4574e4add95f40e7b5ed617761f63453.png?resizew=91)
![](https://img.xkw.com/dksih/QBM/2023/4/15/3216884028104704/3217150769397760/STEM/7837ae9b93d646fa8f0a580e0eb955b3.png?resizew=98)
![](https://img.xkw.com/dksih/QBM/2023/4/15/3216884028104704/3217150769397760/STEM/4a1e3d71f0374e0ea9fa486580af700c.png?resizew=104)
(5)向恒温恒容的密闭容器中充入等物质的量的
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/f5547e0098754a8e3f31bae5d5bcb4dd.png)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/1e762a80c1216318892c2155bef79681.png)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/9110e80d125190c4b5bed606e1fc2220.png)
![](https://staticzujuan.xkw.com/quesimg/Upload/formula/9110e80d125190c4b5bed606e1fc2220.png)
![](https://img.xkw.com/dksih/QBM/editorImg/2023/4/22/667fe85c-ba5e-4d04-8030-952f0cff84ad.png?resizew=367)
A.第一层固态冰中,水分子间通过氢键形成空间网状结构,密度比液态水小 |
B.第二层“准液体”水分子之间形成的氢键较第一层多 |
C.当高于一定温度时,“准液体”中的水分子与下层冰连接的氢键断裂,产生“流动性水分子”,使冰面变滑 |
D.冰熔化成水的过程,是![]() ![]() |
A.![]() ![]() |
B.不同状态的镁中失去最外层一个电子所需能量:![]() |
C.常温下![]() ![]() ![]() |
D.在一容积可变的密闭容器中反应![]() ![]() |
A.该反应在任何条件下都能自发进行 |
B.反应的平衡常数可表示为K=![]() |
C.使用高效的催化剂可以降低反应的焓变 |
D.其它条件不变,增大![]() |
A.2N2(g)+O2(g)=2N2O(g) ΔH=+163 kJ·mol-1 |
B.2Ag(s)+Cl2(g)= 2AgCl(s) ΔH=-127 kJ·mol-1 |
C.2HgO(s)=2Hg(l)+O2(g) ΔH=+91 kJ·mol-1 |
D.2H2O2(l)=O2(g)+2H2O(l) ΔH=-98 kJ·mol-1 |